In ordinary non-technical English, only the word "average" is used, and it refers to a calculation consisting of the sum of a set of numbers divided by the count. The average of 50, 60, and 100 is (50 + 60 + 100) / 3 = 210 / 3 = 70.
In mathematics and statistics, "mean" is considered to be a better word to use. There are at least three different kinds: the arithmetic mean, the geometric mean, and the harmonic mean. If the kind isn't specified, it means "arithmetic mean" which is the same thing as the ordinary "average."
The arithmetic mean is one measure of the center of a cluster of values. It is usually contrasted with the "mode," which is the most commonly occurring value, and the "median," which is the halfway point--half the values in the group lie above it and half lie below it. If there are three people in a room, and one has a net worth of €100,000, one has a net worth of €200,000, and one is Michelle Ferrero with a net worth of €18.5 billion, their median net worth is €200,000 but their mean net worth is €6,166,766,666
In finance, "average" can mean "compound average growth rate" which is actually the geometric mean of the percentage growth of an amount of money. If a mutual fund earned 10% in 2011, 20% in 2012, and 30% in 2013, then the three-year "average" return would be, not 20%, but 19.72%.
In ordinary, but somewhat literary English, "mean" can just mean some midway path or course, most commonly in the phrase "golden mean"--the best, moderate, in-between path.