"Блин" can expresses a wide range of emotions from admiration to dispair depending on situation and intonation, for example:
1. Imagine that you went bread shopping, and on your way you noticed that you had forgotten to take the money. You say “Блин, а кошелёк-то!..” (“Блин, my wallet!..”)
2. If the doors of the train close in front of you in the tube you say “Блин!” ("F*ck!")
3. You open your e-mail box and you see that it is full of spam messages. You say “Блин, достал уже этот спам!” (“Блин, I am fed up with this spam!”)
4. If you envy your friend who says that they have visited Pink Floyd show, you can say “Блииин! Круууто!” (“Блииин! That's so cool!”).
5. You are stuck in a traffic jam: “Ну всё, блин, застряли” (“That’s it, блин, we are stuck”).
... and so on =)