Hello Stephen,
In English you refer to persons using "who" ,while you use "which" to refer to things.
In Spanish it is different ,you use "que" to refer to both persons and things.
So 'que' means 'who' or 'that':
El hombre que vino ayer --
The man who came yesterday
la chica que conoció durante las vacaciones
The girl (that) he met on holiday
It means also 'which' or 'that':
el coche que compré .
The car (that or which) I bought.
el libro del que te hablé
The book (that or which) I spoke to you about .