'I am watching a film...' is more natural/correct, but natives may use 'see' also in the context of films. This may almost be idiomatic because in the past people would only watch films at a movie theater or at some kind of event. An old phrase is 'to see a picture,' where 'picture' is synonymous with film/movie in old- timey lingo. Generally, sticking to 'watch' will be safest, however.
The following are valid expressions:
'We're going to see a film.'
'We're going to watch a film.'
'I can't meet you at 5 pm because I'll be seeing a film.'
'I saw that film.'
Fun but grammatically incorrect regional expression: 'I seen that film.'