"The ink can be traced back to 400 years before"
This is a passive construction, implying the an unnamed agent can tracce the ink. I think someone is confusing before with earlier. Other than that it is correct and understandable.
"The ink traced back to 400 years before."
This sentence uses trace in active voice, and it not correct. Someone has to trace the ink back 400 years. The word, before, is redundant and not needed because the word, back, already means before.