“Police” usually refers to more than one person, so it is usually “notionally plural”. For the word “police”, this is even true in American English, which usually avoids the notional plural in favor of the “formal” singular. For example: British “The band are playing well tonight”* versus American “The band is playing well.”
Note that the words policeman / policewoman / police officer are singular, and can be made plural in the usual way. Other singular words are: the police department, the police force, etc.
*Note: UK speakers sometimes use the singular, if it is notionally singular.