To unspring something is to let it loose as if it was released by a spring. It is not an actual word, but most people will understand it.
In the excerpt that you give, the main character, Yossarian, is given the job of censoring letters from servicemen to their families. He has made a game out of this boring job and is trying to see or create patterns by his censorship. By blacking out some words, he can change the meaning and the rhythm of the letters. So by 'unspringing rhythms', he was using his blackout censorship pen to unleash, release new rhythms in the letters, rhythms and meanings that were not intended by the servicemen that wrote them.
Hope I didn't confuse you.