Some of this info is from the Merriam-Webster.
"As for" means "in regard to" or "concerning"
Ex: "He's here. As for the other people, they'll arrive later."
However, it would sound weird to say "He's here. Concerning/In regard to the other people, they'll arrive later."
I think you would use "As for" when you're shifting focus (in this case, shifting focus from he, who is already here, to the others, who will arrive later).
"As to" means "about".
Ex: "I'm at a loss as to how to explain the error."
Ex: "There is a disagreement as to the causes of the fire."
Ex: "I remained uncertain as to the value of his suggestions."
It's hard to explain the subtle difference. "As to" is more formal than "about". You could replace "as to" in any of these sentences with "about" and not change the sentence structure. I would actually say "about" for the second two sentences, not "as to". I think the biggest difference is formality and they are interchangeable, but there are probably some certain circumstances where "as to" works better.
Because you could replace "as to" with "about" in these sentences, you could also replace it with one of "about" 's synonyms (regarding, concerning, in regard to, etc.).
"As to" has another meaning. It can also mean "according to" or "by"
Ex: "The eggs are graded as to size and color".
If you used "according to" or "by" in this sentence, they all mean the exact same thing.
From the dictionary:
In terms of means with regard to the particular aspect or subject specified.
"replacing the printers is difficult to justify in terms of cost"
I hope this helps! A lot of these are really similar and I'd say the only way to fully understand the nuances and just intuitively know what sounds right is to practice English! Listening, speaking, etc. Of course, you can study, and read what I've written, and that will definitely help, but to just intuitively know, speaking and listening are what will help you!