it depends on the situations, for example, when a group of children are playing together and a new guy is coming, then they may introduce each other by asking "你叫什么名?", it sounds casual here; one more situation, when a police is interrogating a suspect, he can also ask "你叫什么名?", which sounds very formal and iron-handed. "怎么称呼" is used, however, on occasions of first time meeting between adults or business circumstances.
As an adult, you should always use the latter to people unless you are speaking with a child, only in that case, you can use the former to shorten the distance between you and the child.
Hope this can do for you.