он/она болит
они болят
These forms mean "it hurts / they hurt" in relation with body parts:
Мои ступни болят (ступни это они, female plural) = My feet hurt.
Голова болит (голова это она, female singular) = My head hurts.
«Ты болишь» (singular) или «вы болите» (plural) are possible as address in literature:
You, my head, hurt.
You, my fingers, hurt.
Never seen in real life.
Болеть это to be sick (or ill).
Я болею = I am sick.
Он/она болеет = He/she is sick.
Они болеют = They are sick.
Etc.