어느새: before one knows
어느새 가을도 벌써 끝나간다;
Even Autumn is almost over already. (surprised how fast the time goes by, upon realizing it all of a sudden)
길고양이에게 한동안 먹이를 주었더니 어느새 가족이 되어버렸다.
I fed a stray cat for a while and he became a member of the family. (It somehow happened naturally)
어느샌가 is very similar to above, but emotionally stronger.
And no, 누구 & 누군가 are vastly different as you must already know.