미리 is beforehand, in advance etc..
doing something before some events happen.
ex)
미리 자리를 잡아두다
reserve a seat beforehand
넌 미리 나에게 말을 했어야 했다
You should have told me beforehand.
짐은 미리 보내라.
Send your baggage in advance.
먼저 earlier.before...
first or earlier at sequence
ex)
내가 그보다 먼저 왔다
I came earlier than he did. / I arrived before he did.
먼저 도착하는 순서대로 나오다.
First come, first served.
중요한거 먼저 해라!
Do important thing first!