Do you want to study pronunciation or spelling?
If you want to learn correct pronunciation, don't use written English words. The English spelling system is not 1:1. You can use an app like Anki, where you make your own flashcards. The flashcards can be picture + audio, no written word. So you can learn correct pronunciation first. (I find this useful with Chinese words, where there is no "spelling." I learn to say the word first, writing comes later.)
If you already know how to pronounce many words correctly and want to learn correct spelling, yes, there are some "rules" but not many and they aren't very helpful anyway. In middle school, we had a weekly list of "spelling words" that we had to memorize and then we had a weekly "spelling test."
My husband, a native English speaker, once told me that he learned how to spell by looking up in the dictionary every word that he couldn't spell. The process was slow but it worked.