If it's "きみ," we don't use/hear the word so often in daily conversation.
If it's "くん" in "(boys' names)+君," then we use/hear it everyday.
When you hear きみ, it's probably when teachers call students at school. It can be used for boys and girls.
You don't use 君(くん) for girls' names. :)
If I got your question wrong, I apologize and please let me know! ^^