1) "是个"means "is a". It's not a word. "可我却是个性格开朗." should be "可我却是个性格开朗的人" = "but I am an optimistic man" or "可我却是性格开朗的" ="but I am optimistic"
2) And yes, "却"is a frequently used word, and most of the time a coordinate conjunction which means"but" or "while" or"however".
3) To understand correctly a Chinese sentence, you have to analyze the structure, get clear where are the subjects, the objects,predicate verb,predicatives,link verbs,qualifiers, determiners,adverbials and some other elements. Pay attention to the logic of sentences. The meanings are usually expressed by the logics.