You use "Bueno" when something is okey like "This place is really good!"---In spanish:"Este lugar es muy bueno!" or "I have a good idea"---"Tuve una buena idea".
Now,you use "Bien" when someone or you DO something okey, like:
"How was the school?----Good" In spanish: "Como te fue en la escuela?"-----"Bien" (I dont know if you can answer that in english with just a good, but in spanish yes you can.
or when someone ask you "how are you?"In spanish "Como andas?"-----"Bien" (That BIEN is like I am fine)