Not too much difference, just like "at once" and "immediately" in English. 立即 is a bit more formal than 立刻。
November 8, 2017
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两者并无明显区别。
※补充:立即=马上=立刻=即时=随即=速即(不常用)=立时(不常用)
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November 12, 2017
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