It is not correct, but I don't really understand the meaning, so I can't easily correct it for you.
I'll try to explain. It is not a complete sentence because it doesn't have a subject. Who is releasing the money?
Any of the following would be correct if they are what you are wanting to say:
I am releasing an amount of 10,000 as imprest money.
Or
We (or you or they) are releasing an amount of 10,000 as imprest money.
Or
He (or she or it) is releasing an amount of 10,000 as imprest money.
There are other things that might be correctly added to. For example:
Please begin by releasing an amount of 10,000 as imprest money.
Or
His biggest mistake was releasing amount of 10,000 as imprest money.
I hope that makes it clear that the problem is that it is not a complete sentence. How you should complete it depends on what you are trying to say.