"Щас" is a way to pronounce "сейчас" in informal speech. You will not see it in writing, except for places like web chats etc where people don't care about their spelling and like to make words look just the way they are pronounced in informal speech.
"Сейчас" means now, at the present moment. It's also used as "Just a minute" .
"Теперь" means "now", but implies a contrast to something in the past : "Раньше я не любила классическую музыку, а теперь люблю".
"Пока" can mean "bye" (informal), or "while": "Пока дети смотрели телевизор, бабушка готовила ужин". It can also mean "so far/yet" : Я пока не хочу есть - I'm not hungry yet.