What's more natural?
He painted red the walls, the window frames and the ceiling.
He painted the walls, the window frames and the ceiling red.

Question

Answer

He painted the walls, window frames and ceiling red. (Always cut as many extraneous "filler" words as possible, in this case, the extra "the's" can go.)

Answer

Second

Answer

He painted the walls, window frames and the ceiling red.

Answer

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Answer

The second option