"Decision" being "well-calibrated" can indeed make sense depending on the context.
"Well-calibrated" typically implies that something is accurately set or adjusted according to a standard or requirement. In the context of decision-making, it could mean that the decision is well-informed, balanced, and aligned with the circumstances or objectives at hand.
For instance, you might say:
"The decision was well-calibrated, taking into account both short-term gains and long-term consequences."
However, whether it sounds natural or not could depend on the specific context in which you're using it. If you're unsure, you might want to provide more details about the decision and the situation to get more targeted feedback.