It sounds like [psi]
In english, it sounds just like in the word "ps-ychology"
٢ سبتمبر ٢٠١٥
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The Best Answer is:
To pronounce "Ψ/ψ" sounds like a "Psi", in which you need to epmphasise in the last vowel -i.
Alternatively, I would highly recommend this website in which you can clearly listen to the way we pronounce "Ψ/ψ" http://www.howjsay.com/index.php?word=psi
Hope this might have helped!