hi,
welcome
yes
1.choose some one for chatting.
2.click on his/her name & go to his/her page.
3.if he/she was online you can click the icon ( chat now) at right top of his/her page.
4. new window will open after connection you can write your massage in the blue box in the middle of that window .
5.if he or she wants he/she can reply you.
GOOD LUCK