I wanted you to put on the coat.
你不穿 means you refused to .
你非不穿 means you strongly refused to.
Here, 非 is used to emphasis on the action of not doing something.
2017年4月7日
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非 = not 不 = not So a double negative becomes positive i.e. to mean "must"
2017年4月12日
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'非'是个语气词 '非不'stubbornly insist not to (wear the clothes)