Both are invitations to talk, but here's how I see the difference:
Talk to me = you have something to tell me.
Talk with me = lets discuss something, I want to hear you talk and I also have things to say.
2010年10月24日
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There is not much difference, but just a little difference in emphasis. When you say "talk to me" you are emphasizing just having a communication with a person without regard to a particular subject. When you say "talk with me" there is an inference that there is a particular subject in mind to talk about.
2010年10月24日
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Talk to me - "I want to hear what you have to say to me. Please tell me."
Talk with me - There is some issue or feeling between the two people
that they will talk about together. (or) Maybe the person
who said this needs some company or comforting...
2010年10月24日
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Next time, you might write a complete sentence that includes the phrase. That would be helpful. ^^