What's the equivalent of 'Nice to meet you' when you talk to someone first time over phone? Say I talk to my boss for first time who I never met in person.

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"It's a pleasure to finally speak with you" or "it was a pleasure talking to you" if the call is over and you are speaking with them at a later time.

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It's a pleasure to speak with you.
Pleased to meet you

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"Nice to meet you" is very common.

"It's a pleasure to meet you."

"Pleased to meet you."

"It's a pleasure to make your acquaintance."  (very formal)

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It's a pleasure to speak with you. (During the conversation)

It was nice talking to you. (At the end of the conversation)

Great speaking with you (At the end of the conversation)

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