沸水 is rare in spoken Chinese
开水 is very common, could be boiling water or boiled water,you need figure it out by context.
eg,1: my feet had been burnt in 开水 few years ago/ boiling water.
2:"hi,waiter,can i have some 开水?” --Now,the water couldn`t be boiling whatever how hot it is. and it could be hot 开水,could be cold 开水。the resturant will simply bring you a pot and some glasses... just suit yourself