More or less we are (Spaniards) used to use "mujer" = woman and "señora" = mrs. Well, the main difference (as far as I see) is that we use "señora" for an older woman than "mujer". In addition, "señora" is more respectful than "mujer".
Más o menos estamos (los españoles) acostumbrados a usar "mujer" para la palabra inglesa woman y señora para la abreviatura inglesa "mrs". Además, "señora" es más respetuoso que mujer.