They mean pretty much the same, but direct translation for each sentence is a bit different :).
나는 피가 무섭다(Adjective) = As for me, blood is scary
나는 피를 무서워하다 (Transitive Verb) = I find blood scary.
Some Korean words can be confusing in terms of how they look like adjectives but are actually verbs and vice versa :)!
e.g) 좋다 = to be good
좋아하다 = to like
Hope that helps :)!