>> "at all" is only used in negative sentence or question << That's not true. But mostly yes.
Although, the first "negotiators" sentence implies a negative meaning, meaning they probably won't make it. The second "Spanish" s has a more implied and slight negative meaning, because "a little" usually makes people who expect a postive answer disappointed.
The two above are not positive "positive-sentence" examples but actually somewhat negative-"at all" as an adverb means substantially, radically, at the very beginning, fundametally, first off, etc.
The Chinese educators are right at all. The Chinese educators get it wrong at all.
It could also equal of "anything", "any possibility", if you get any information from Professor B at all, you let me know.