Arimasu vs Arimasen
Im slightly confused on when you use either one, or what the difference is.

Question

Answer

The difference is that あります (arimasu) is the affirmative form of the verb and ありません (arimasen) is the negative.

For example:

えんぴつがあります。
enpitsu ga arimasu. 
(I have a pencil)

えんぴつがありません。
enpitsu ga arimasen.
(I don't have a pencil)

I think this should be clear, but if you have any questions, please ask.

Answer

Essentially one is positive and one is negative.  If someone asked you if you had something and you replied with Arimasu, then you'd be telling them you have it, and if you used Arimasen, then it'd be telling them you don't have it.

Verpassen Sie nicht die Gelegenheit, bequem von zu Hause aus eine Sprache zu lernen. Stöbern Sie in unserer Auswahl an erfahrenen Sprachlehrern und melden Sie sich jetzt zu Ihrer ersten Unterrichtsstunde an!