妹に会いに行くつもりです
verb + "に" + verb. Japanese often use this grammer. It is difficult to explain but, it expresses a series of movements. for example,
会いに行く 会う+行く
食べに行く 食べる+行く
遊びに行く 遊ぶ+行く
In the same way, 〜に+verb is seen in " adjective + verb. here are some example.
好きになる 好き+なる
上手になる 上手(じょうず)+ なる
it may confuse you, but please try to search more if you couldnt understand.