englishinfocus1.googlepages.com/Assure_Ensure_Insure.htm
copy and paste that into your address bar and press open/save when prompted.
it's a useful guide to the differences between ensure, assure
secure is quite different to the other three.
secure: 1) to make secure: to protect, free from attack/danger. eg. the money was made secure.
2) stable/firm, not likely to fail. eg. the house was very secure.
hope this has helped (: