Finishing up Sonia's correct answer... :)
It's actually the syllables "-tion" and "que-" you have to look at: "ti-on" gets tiring to say, so we slur it into "shon" or "chon" (nation, federation, question).
Q is always followed by a U in English (only exceptions are borrowed words and acronyms), giving a "kw" sound. So it's "ques-tion", instead of "qu-es-tion".
Extra note: some words have different syllables between American and British styles, mainly because the British will drop a syllable for easier speech, where Americans may prefer reading the word as phonetically as possible. A classic example is "comfortable": pronounced "com-for-ta-ble" in America and "comf'-ta-ble" in the UK.