Jürgen Klopp is the subject, 'announces' is the verb : 'Klopp announces . . exit' ie departure [the object] 'in blow' i e disappointment 'for [the club's] owners'. 'shock' ie. unexpected describes 'exit'. The 'exit' is from Liverpool Football Club [the North American newspaper calls it a soccer club]; 'Liverpool soccer club' has been made in to
an 'honorary adjective' also describing 'exit'.
This style of writing is normal for newspaper headlines but requires familiarity with English to decipher. You can see that articles ['a' blow, 'the' US owners] are omitted, as is the possessive pronoun [ 'his' exit], and the preposition 'from' Liverpool soccer club.