If you rephrase the question to include he/him, then select which of those 2 sounds better, that will help you tell which is correct. For example :Can I say ”To whom would you like to speak?”? Ask it as" Would you like to speak to he/him? " In this case, "him" sounds better so you would use whom. Now for example you wanted to see if it should be "Who/whom is home?" so you would rephrase it as "is he/him home?" , and "he" is correct, so you would use "who" to ask "Who is home?"
Also, you wouldnt start a sentence with "whom".
But as Jmat said, most people stopped using "whom" altogether, which is kind of strange if you think about it. Its kind of like how most people dont know when to use "him and I" or "me and him".