In so many cases these words can be used interchangeably.
This is the only distinction that I can think of to make:
"To accomplish" simply means "to complete", as in "I've accomplished a lot of work today". It suggests that a person has simply completed an action.
However, "To achieve" and "to attain" at times almost suggest a slight ownership to me, as in
"He's achieved a high level of knowledge on that subject" or "He's attained a high level of knowledge". (