âCouldâ is possible but changes the meaning in an important way.
Whether he was doomed, you couldnât tell. (You are making the determination of his status in the past)
Whether he was doomed, you canât tell. (You are making the determination now)
Replacing ânotâ with âneverâ extends the time period.
You can never tell. (Now, and in the future)
You could never tell. (In the past, and after that time in the past)