"Ваш" и "Наш"- possessive pronouns. The question is Whose?(Чей?).
For example, whose is this phone?- It's ours- Он наш.
whose is this pen?- It's yours-Он ваш.
"Нас" и "Вас"-use only in genitive, accusative, prepositional cases.
For example, where were they?-Они были у нас.
where were they?-Они были у вас.