Go to 'Find a Tutor' and choose the language you want to learn, then, for 'Availability,' choose 'Now' and turn on 'Instant Tutoring'.
Edited
Sorry - my mistake - you are looking for the free live sessions. I don't know how to find those.
2018年11月6日
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Italki rules prohibit community tutors and professional teachers from giving free lessons.
Perhaps you are looking for a conversation partner?