Sentence one, China appears to make the most of next year's Olympic Game.
does not make sense
compare: China wants (NOW) (present verb wants) (something in the future) to make the most of next year's Olympic Game.
Sentence two, China appears set to make the most of next year's Olympic Game.
China appears set (or ready) (NOW) (present verb appears) (an action in the future) to make the most of next year's Olympic Game.
Note: to appear takes an adjective, not a noun
he appears fat
he appears lazy
he appears angry
etc.
set is an adjective, often followed by "to do something", like sentence 2
or example: the old man is set in his ways. Here set = established, rigid
or the dinner table is set. set = ready, prepared
are you all set for the exam.