Dare means to have the courage to do something: "Would he dare to tell the true story?" It can also be used for a challenge: "I dare you to face the danger alone?"
Daren't is a contraction of "dare not." I seldom hear this word used in English conversations where I live in Canada. If it is used in a sentence an example could be: "They daren't drive the car that they stole if the police are searching for them."