안 means that you have ability to do sth, but you don't do that. 못 means that you don't have ability to do sth, so you can't do that.

안-is not~나는 안배고파요. I'm not hungry. 못-is can't~한국어 잘 못해요. I can't speak Korean well.

안是主观否定，是能做而不做。 못是客观否定，是不能做。