Also, it's impossible to be accurate with such a statement. Diligence is subjective and immeasurable. You can't really quantify it in concrete terms as to be able to say one person is "three times" more diligent than another, unless you're specifically talking about an outcome (you could say, "he accomplished more than three times the amount of work").
Instead, for an abstract term like "diligence", you should say,
"He is more diligent than me."
or,
"He is much more diligent than me."
You can also use other non-quantifiable words to express emphasis:
"He is way more diligent than me."