顔 means just "Face" but 面 means like "Side"
for example 顔面(face side) 背面(back side)
actually, 面 has mean "Face". but it's a little bit old and sometime offensive.
October 12, 2018
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人間の顔面の形や表情を表す意味の場合、
面【つら】は顔【かお】よりぞんざいな言い方です。
In context of human face shape or expression, 'tsura' has impolite, rude or careless savor.
October 12, 2018
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Hi,
They both can mean face, but 面 is pronounced as つら (tsura).
And it is kind of a rough / dirty way to say face.
October 12, 2018
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