Awake is an adjective, so it describes a state of being conscious and aware of your surroundings. Wake is a verb and describes the action of waking up - going from being asleep to being awake. It can also mean causing somebody else to arise from their sleep. For example, "I will wake you in the morning".
Also, "I awoke one morning" / "I have awoken" - these are both past tense forms of the verb "to awaken". The phrasal verb "to wake up" can also be used, either to describe waking yourself up or waking somebody else up from their sleep. E.g. "I will wake up at 8am" or "I will wake you up at 8am".
The main thing to remember is that "awake" will always be used as an adjective, but "wake" is a verb.