Depending on the grammar guide or grammar expert that you consult, you may get different advice. Many teachers will tell you that "I don't mind him watching TV" is wrong and that the correct way to say/write it is "I don't mind his watching TV". They claim that in this sentence the word "watching" is a gerund, which is a type of noun, and that object pronouns such as "him" can't modify nouns, only possessive pronouns can do that.
However, outside of literature and formal writing it is more common to say "I don't mind him watching TV", and many people will consider this to sound more natural and normal, and they will consider "his watching" to sound more formal or old-fashioned.
My advice: in formal or academic writing try to avoid saying something like "I don't mind him watching TV", and in casual writing or speech do as you wish.