'Chilling' has various meanings depending on the context and usage. In formal English it represents 'Coldness, Becoming Cool, Falling in Temperature' or 'Scary, Frightening'. But in the form of a 'Slang' it is generally used to mean 'Relaxing, Becoming Calm'.
So in your sentence the context is 'listening to music'. Its a common usage in informal & casual English (Slang). It would mean 'Relaxing, Becoming Calm, Soothing the Senses'.
'Doing nothing very serious but just relaxing while listening to music.'
Hope it helps.